
by Robert Marcos
I was dumbfounded to hear a scientist with the U.S. Geological Survey say, “I wish we could date this water so we’d have a better idea where it came from”. We were standing alongside a tiny creek that led into Colorado’s White River, and the scientist was essentially wondering if the water in the stream came from rainfall, or had risen from a shallow aquifer. Generally rainfall would be “younger” and water from aquifers would be older – sometimes by many thousands of years. But how could anyone possibly determine the age of water?
Answer: by analyzing its chemical composition.
The USGS dates groundwater using chemical and isotopic tracers whose concentrations change in known ways over time in the atmosphere and then get preserved in recharging water. For young groundwater—typically less than about 50–70 years old—USGS commonly uses substances like chlorofluorocarbons (CFCs), sulfur hexafluoride (SF₆), and tritium and its decay product helium‑3. These are measured in specialized facilities such as the Reston Groundwater Dating Laboratory, which analyzes dissolved gases and transient tracers in samples from wells and springs. The key idea is that atmospheric histories of these tracers (for example, industrial production curves for CFCs or tritium from nuclear weapons testing in the 1950s–60s) provide a time stamp that can be matched to what is found in the water.1
One example is tritium-based age classification – where a single measurement of tritium is used to classify groundwater as “modern” (recharged in 1953 or later), “premodern” (before 1953), or a mixture of the two. The year 1953 roughly marks the onset of elevated tritium from atmospheric nuclear testing, making it a convenient boundary between older, background conditions and post‑bomb‑pulse recharge. By comparing measured tritium to location‑ and time‑specific thresholds, USGS can quickly determine whether a sample reflects recent recharge that may carry contemporary contaminants or older water that has been isolated from the modern surface for decades or longer.
For slightly older water—hundreds to tens of thousands of years—USGS uses longer‑lived isotopic tracers such as radiocarbon (carbon‑14) dissolved in inorganic carbon. Radiocarbon decays predictably over time, so its remaining fraction in groundwater indicates how long it has been since the water equilibrated with atmospheric carbon at the surface. At even greater ages, other isotopes and noble gases may be used to extend the window into tens of thousands of years or more. No single method is perfect; each tracer has limitations, such as contamination from local sources, mixing of waters of different ages, or chemical reactions that alter concentrations. As a result, USGS often applies multiple tracers together and interprets them with groundwater flow models to better constrain age and understand the distribution of ages in a well or discharge area.
USGS dates groundwater because age is fundamental for managing water resources and assessing vulnerability to pollution. Age indicates how quickly water moves through the subsurface, how long it will take for land‑use changes to affect wells and springs, and whether contaminants like nitrates, pesticides, or per‑ and polyfluoroalkyl substances (PFAS) reflect current practices or legacy inputs. By linking age to contaminant trends, managers can judge whether improvement efforts will show benefits in years, decades, or even longer. Age information also supports sustainable yield estimates, helps distinguish short‑term variability from long‑term change, and reveals dependencies on very old water that may take thousands of years to replenish.










